Crystal Field Theory and Gems--Guided Inquiry

Submitted by Adam Johnson / Harvey Mudd College on Sat, 05/14/2016 - 21:42
Description

The colors of transition metal compounds are highly variable. Aqueous solutions of nickel are green, of copper are blue, and of vanadium can range from yellow to blue to green to violet. What is the origin of these colors? A simple geometrical model known as crystal field theory can be used to differentiate the 5 d orbitals in energy. When an electron in a low-lying orbital interacts with visible light, the electron can be promoted to a higher-lying orbital with the absorption of a photon. Our brains perceive this as color.

Ligand Field Correlations for Square Pyramidal Oxovanadium(III)

Submitted by Matt Whited / Carleton College on Fri, 04/22/2016 - 10:37
Description

Students work in groups to derive the ligand-field diagram for a square-pyramidal vanadium(III) oxo complex using octahedral V(III) as a starting point. The activity helps students to correlate changes in orbital energies as a function of changing ligands and geometry as well as rationalizing why certain geometries can be particularly good (or bad) for particular complexes. The activity also helps students see why oxo complexes of early metals are frequently best described as triple bonds.

Nanomaterials Chemistry

Submitted by Anne Bentley / Lewis & Clark College on Wed, 03/23/2016 - 15:49

This list includes a number of LOs to help in teaching nanomaterials subjects; however, it is not exhaustive.

Updated June 2018.

ColourLex - a colorful website!

Submitted by Vanessa / Albion College on Tue, 03/15/2016 - 13:49
Description

ColourLex (colourlex.com) is an amazing website that mixes chemistry and art. The creators of this website have extensively catalogued paintings and the pigments that were used to create them. The pigments range from artificial to natural and organic to inorganic. You can search for the specific combination that you want to see.

Writing Lab Reports

Submitted by John Lee / University of Tennessee Chattanooga on Wed, 03/02/2016 - 14:14
Description

Each spring semester I take on the task of teaching and grading full lab reports for my senior advanced inorganic chemistry class. For most this is their first experience writing a document of this magnitude as most other labs they have previously taken require either lab report sheets or the occasional abbreviated lab memo. As I read their lab reports each year I am reminded both how challenging it is to teach writing (more specifically scientific writing) and to grade the reports objectively.

d orbital splitting in Trigonal Pyramidal Field

Submitted by Sheila Smith / University of Michigan- Dearborn on Sat, 02/27/2016 - 12:55
Description

This is a short critical thinking exercise that I use to assess whether my students have understood where the d orbital splitting in Octahedral and Tetrahedral geometry  comes from.  I do it at the beginning of the class after we discuss CFT/LFT in Oh and Td compounds. 

Point Group Battles Activity

Submitted by Darren Achey / Kutztown University on Thu, 10/15/2015 - 11:48
Description

In this activity, a pair of students are show an object or molecule and are asked to determine the point group before their competitor.

Working with Catalytic Cycles

Submitted by Matt Whited / Carleton College on Mon, 09/28/2015 - 14:05
Description

Students work in groups to identify relevant steps and intermediates in 3 catalytic cycles, all the while considering bonding (and electron counting) factors.  Following assignment of these steps and intermediate species, the students consider several questions related to catalysis more broadly, particularly the role of each reagent, how to speed up or slow down specific steps, and the importance of regiospecificity in certain steps.