Inorganic Chemistry Spectroscopy Tutorial: Theoretical Principles and Applications, Version 2.0

Submitted by Jason Cooke / Department of Chemistry, University of Alberta, Canada on Thu, 04/01/2021 - 07:34
Description

In the 2000s, we developed an online tutorial that demonstrates the fundamental principles and applications of the various types of spectroscopy that students will encounter in the inorganic chemistry laboratory, namely infrared spectroscopy (IR), nuclear magnetic resonance spectroscopy (NMR) and UV-visible spectroscopy (UV-vis).  With the demise of the original Flash browser plug-in at the end of 2020, a revised version 2.0 has been created to update the source content to HTML5.  The tutorial has been designed as a stand-alone interactive resource that can either

Anion Coordination Chemistry (Bowman-James)

Submitted by Hilary Eppley / DePauw University on Tue, 03/30/2021 - 14:56
Description

Ligands can bind to anions, just as they do to metal ions, and Bowman-James developed these analogies as well as many examples of selective anion binding ligands.  This short slide decks gives background to her work as well as some relevant introductory material.  

Artificial Photosynthesis Using Quantum Dot / Porphyrin Aggregates (Weiss)

Submitted by Anne Bentley / Lewis & Clark College on Sun, 03/28/2021 - 14:17
Description

This literature discussion highlights recent research from the Weiss group in which electrostatically assembled aggregates of CuInS2 / ZnS quantum dots and trimethylamino-functionalized tetraphenylporphyrin molecules were used to selectively reduce carbon dioxide to carbon monoxide.

National ACS Award Winners 2021 LO Collection

Submitted by Shirley Lin / United States Naval Academy on Fri, 03/26/2021 - 12:14

This collection of learning objects was created to celebrate the National ACS Award Winners 2021 who are members of the Division of Inorganic Chemistry. The list of award winners is shown below. 

Proton-Assisted Reduction of CO2 by Cobalt Aminopyridine Macrocycles (Marinescu)

Submitted by Todsapon T. / University of Evansville on Sun, 03/14/2021 - 15:32
Description

Various topics ranging from coordination chemistry, electrochemistry, solid state chemistry and point group and symmetry are discussed from the JACS article published by Smaranda C. Marinescu and her co-workers.  The article describes the conversion of CO2 to CO by using cobalt aminopyridine macrocycle catalysts.

Terminal Uranium (VI) Nitrides: Photoredox Synthesis and Reactivity (Mazzanti)

Submitted by Hilary Eppley / DePauw University on Tue, 03/02/2021 - 12:31
Description

This is one of a collection of learning objects developed to honor the 2021 ACS Award Winners in inorganic chemistry.  Marinella Mazzanti from the Swiss Federal Institute of Technology was awarded the F. Albert Cotton Award in Synthetic Inorganic Chemistry for her outstanding accomplishments in uranium and lanthanide chemistry, including the stabilization of unusual oxidation states and multimetallic cluster synthesis and small-molecule activation. In this paper photoredox chemistry is used to synthesize a uranium (VI) nitride.

reaction of PPh3 with elements--the COVID edition

Submitted by Adam Johnson / Harvey Mudd College on Sun, 02/28/2021 - 15:37
Description

This is a research-like laboratory experience based on the one posted by Brad Wile (linked below). My students are mostly juniors and have had 2 semesters of organic. This spring they are taking the inorganic laboratory virtually, so I wanted to give them a more exploratory lab experience. Their job will be to watch the YouTube videos to see the synthesis and isolated products, and then propose characterization methods they want to employ to identify both the identity and purity of the compounds. 

Development of Expanded Porphyrins (Sessler)

Submitted by Shirley Lin / United States Naval Academy on Wed, 02/24/2021 - 09:24
Description

The LO focuses upon classic articles describing the synthesis and characterization of the first "texaphyrin" compounds.

This LO is part of a special VIPEr collection honoring the 2021 ACS National Award recipients in the field of inorganic chemistry. Jonathan L. Sessler was the recipient of the Ronald Breslow Award for Achievement in Biomimetic Chemistry for the discovery of expanded porphyrins, molecular recognition via base-pairing, pyrrole-based anion binding, and demonstrating the power of this biomimetic chemistry in drug discovery.

5 slides about nomenclature

Submitted by Adam Johnson / Harvey Mudd College on Mon, 02/08/2021 - 18:11
Description

I have never enjoyed teaching nomenclature, but it is certainly important for students to know what is meant when they see a name out there in the wild. I use Gary's excellent in-class activity (linked below) and then follow up with these slides to cement the knowledge in the last 10-20 minutes of class. The first content slide is a list of nomenclature rules from IUPAC but I normally fill in a list of class-generated rules on the title slide before moving to the truth... our in-class rules are often quite close to the published rules.